Operating Conditions of Hollow Fiber Supported Liquid Membrane for Phenol Extraction from Coal Gasification Wastewater

Authors

  • Yao Jie School of Municipal and Environmental Engineering, Harbin Institute of Technology, P. R. China
  • Cai Chao School of Municipal and Environmental Engineering, Harbin Institute of Technology, P. R. China
  • Zhang Dandan School of Municipal and Environmental Engineering, Harbin Institute of Technology, P. R. China
  • You Hong School of Municipal and Environmental Engineering, Harbin Institute of Technology, P. R. China
  • Han Yahong School of Municipal and Environmental Engineering, Harbin Institute of Technology, P. R. China
  • Yang Shuren School of Municipal and Environmental Engineering, Harbin Institute of Technology, P. R. China
  • Guo Hongxia Henan Mechanical & Electrical Engineering College, Xinxiang, Henan, P.R. China
  • Han Bangjun School of Civil Engineering, Heilongjiang University, Xuefu Road, Harbin150090, P.R. China
  • Du Ziwei China Overseas Property Co., Ltd. (Yantai), P.R. China
  • Sjack van Agtmaal Evides Industriewater B.V. Schaardijk 150, 3063 NH Rotterdam, the Netherlands
  • Feng Chunhui Evides Industriewater B.V. Schaardijk 150, 3063 NH Rotterdam, the Netherlands

DOI:

https://doi.org/10.6000/1929-6037.2014.03.02.5

Keywords:

Coal gasification wastewater, Extraction efficiency, Hollow fiber membrane, Scale-up experiments.

Abstract

The extraction and recycling of phenol from high concentration coal gasification wastewater has been studied using polypropylene (PP) hollow fiber membrane and polyvinylidene fluoride (PVDF) hollow fiber membrane as liquid membrane support, the mixture of tributyl phosphate (TBP) and kerosene as liquid membrane phase, and sodium hydroxide as stripping agent in the process of extraction. The experiments investigated the effect of the operating conditions of the hollow fiber supported liquid membrane, such as aqueous phase temperature and the connection forms of membrane modules, on the extraction efficiency of phenol from high concentration coal gasification wastewater. The conclusions obtained from lab scale experiments provided guidance for scale-up experiments. So, in the scale-up experiments, three membrane modules connected in parallel, then three membrane modules connected in series were used to increase the treatment capacity and improve the treatment effect, under the operating conditions of wastewater temperature 20 ˚C, PH 7.5~8.1, flow rate 100 L/h and the concentration of stripping phase 0.1 mol/L, stripping phase flow rate 50 L/h, the extraction efficiency of the PP-TBP supported liquid membrane system was 87.02% and the phenol concentration of effluent was 218.14mg/L. And the phenol concentration of effluent met the requirements of further biodegradation treatment.

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Published

2014-06-02

How to Cite

Jie, Y., Chao, C., Dandan, Z., Hong, Y., Yahong, H., Shuren, Y., Hongxia, G., Bangjun, H., Ziwei, D., Agtmaal, S. van, & Chunhui, F. (2014). Operating Conditions of Hollow Fiber Supported Liquid Membrane for Phenol Extraction from Coal Gasification Wastewater. Journal of Membrane and Separation Technology, 3(2), 100–107. https://doi.org/10.6000/1929-6037.2014.03.02.5

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