Removal of Nickel(II) from Aqueous Solution by Complexation-Ultrafiltration with Polyvinyl Pyrrolidone

Authors

  • Zhixin Chen College of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, P R. China
  • Jianxian Zeng College of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, P R. China
  • Yangen Ding Xiangtan Electrochemical Scientific, Ltd., Xiangtan 411202, P R. China

DOI:

https://doi.org/10.6000/1929-6037.2016.05.03.2

Keywords:

Nickel(II), Polyvinyl pyrrolidone, Complexation, Ultrafiltration

Abstract

This study confers insight into the removal of Nickel(II) from aqueous solution by complexation-ultrafiltration (CP-UF) technique with water-soluble polymer polyvinyl pyrrolidone (PVP). The whole experiment process includes five parts: pre-treatment, CP-UF, concentration, decomplexation and regeneration of polymer. Numerous factors affecting the retention rate of Nickel(II) (RNi) and permeate flux (J), such as pH, loading ratio, transmembrane pressure (TMP), complexation time and added salt have been investigated. In the CP-UF process, RNi reaches nearly 94% while pH of 7, loading ratio of 4, TMP of 1.0 bar, temperature of 250C, complexation time of 30 min are chosen to be the optimal parameters. In the process of concentration, J declines slowly and RNi is very high at loading ratio of 4 and pH of 7. Nickel ion concentration in the retentate solution increases linearly with volume concentration factor. In the process of decomplexation, the decomplexation percentage of nickel(II)-PVP complex reaches 42%. The binding capacity of the regenerated PVP is close to that of fresh PVP, and the recovery percentage of binding capacity is higher than 90%.

References

Fu FL, Wang Q. Removal of heavy metal ions from wastewaters: a review. Journal of Environmental Management 2011; 92: 407-418. http://dx.doi.org/10.1016/j.jenvman.2010.11.011

Mimoune S, Amrani F. Experimental study of metal ions removal from aqueous solutions by complexation-ultrafiltration. Journal of Membrane Science 2007; 298: 92-98. http://dx.doi.org/10.1016/j.memsci.2007.04.003

Cojocaru C, Zakrzewska-Trznadel G, Jaworska A. Removal of cobalt ions from aqueous solutions by polymer assisted ultrafiltration using experimental design approach, part1:Optimization of complexation conditions. Journal of Hazardous Materials 2009; 169: 599-609. http://dx.doi.org/10.1016/j.jhazmat.2009.03.145

Zeng JX, Ye HQ, Hu ZY. Application of the hybrid complexation-ultrafiltration process for metal ion removal from aqueous solutions. Journal of Hazardous Materials 2009; 161: 1491-1498. http://dx.doi.org/10.1016/j.jhazmat.2008.04.123

Desai KR, Murthy ZVP. Removal of silver from aqueous solutions by complexation-ultrafiltration using anionic polyacrylamide. Chemical Engineering Journal 2012; 185-186: 187-192. http://dx.doi.org/10.1016/j.cej.2012.01.072

Barakat MA. New trends in removing heavy metals from industrial wastewater[J]. Arabian Journal of Chemistry 2011; 4(4): 361-377. http://dx.doi.org/10.1016/j.arabjc.2010.07.019

Reck BK, Müller DB, Rostkowski K, Graedel TE. Anthropogenic nickel cycle: insights into use, trade, and recycling. Environmental Science and Technology 2008; 42: 3394-3400. http://dx.doi.org/ 10.1021/es072108l

Denkhaus E, Salnikow K. Nickel essentiality, toxicity, and carcinogenicity. Critical Reviews in Oncology-Hematology 2002; 42: 35-56. http://dx.doi.org/10.1016/S1040-8428(01)00214-1

Qiu YR, Mao LJ. Removal of heavy metal ions from aqueous solution by ultrafiltration assisted with copolymer of maleic acid and acrylic acid. Desalination 2013; 329: 78-85. http://dx.doi.org/10.1016/j.desal.2013.09.012

Zeng JX, Sun XH. Recovery of Tungsten (VI) from Aqueous Solutions by Complexation-ultrafiltration Process with the Help of Polyquaternium. Chinese Journal of Chemical Engineering 2012; 20: 831-836. http://dx.doi.org/10.1016/S1004-9541(12)60406-6

Khosa MA, Shah SS, Feng X. Metal sericin complexation and ultrafiltration of heavy metals from aqueous solution. Chemical Engineering Journal 2014; 244: 446-456. http://dx.doi.org/10.1016/j.cej.2014.01.091

Ennigrou DJ, Gzara L, Ben Romdhane MR, Dhahbi M. Cadmium removal from aqueous solutions by polyelectrolyte enhanced ultrafiltration. Desalination 2009; 246: 363-369. http://dx.doi.org/10.1016/j.desal.2008.04.053

Mimoune S, Belazzougui RE, Amrani F. Purification of aqueous solutions of metal ions by ultrafiltration. Desalination 2007; 217: 251-259. http://dx.doi.org/10.1016/j.desal.2007.01.016

Bodzek M, Korus I, Loska K. Application of hybrid complexation–ultrafiltration process for removal of metal ions from galvanic wastewater. Desalination 1999; 121: 117-121. http://dx.doi.org/10.1016/S0011-9164(99)00012-0

Osipova EA, Sladkov VE, Kamenev AI, Shkinev VM, Geckeler KE. Determination of Ag(I), Hg(II), Cu(II), Pb(II), Cd(II) by stripping voltammetry in aqueous solutions using complexing polymers in conjunction with membrane filtration. Analytica Chimica Acta 2000; 404: 231-240. http://dx.doi.org/10.1016/S0003-2670(99)00713-8

Shao J, Shu Q, Davidson J, Li W. Recovery of nickel from aqueous solutions by complexation-ultrafiltration process with sodium polyacrylate and polyethylenimine. Journal of Hazardous Materials 2013; 244: 472-477. http://dx.doi.org/10.1016/j.jhazmat.2012.10.070

Trivunac K, Stevanovic S. Removal of heavy metal ions from water by complexation-assisted ultrafiltration. Chemosphere 2006; 64: 486-491. http://dx.doi.org/10.1016/j.chemosphere.2005.11.073

Periasamy K, Namasivayam C. Removal of nickel(II) from aqueous solution and nickel plating industry wastewater using an agricultural waste: Peanut hulls. Waste Manage 1995; 15: 63-68. http://dx.doi.org/10.1016/0956-053X(94)00071-S

Baticle P, Kiefer C, Lakhchaf N, Leclerc O, Persin M, Sarrazin J. Treatment of nickel containing industrial effluents with a hybrid process comprising of polymer complexation-ultrafiltration-elec-trolysis. Separation and Purification Technology 2000; 18: 195-207. http://dx.doi.org/10.1016/S1383-5866(99)00063-5

Aliane A, Bounatiro N, Cherif AT, Akretche DE. Removal of chromium from aqueous solution by complexation - ultrafiltration using a water-soluble macroligand. Water Research 2001; 35: 2320-2326. http://dx.doi.org/10.1016/S0043-1354(00)00501-7

Downloads

Published

2016-10-25

How to Cite

Chen, Z., Zeng, J., & Ding, Y. (2016). Removal of Nickel(II) from Aqueous Solution by Complexation-Ultrafiltration with Polyvinyl Pyrrolidone. Journal of Membrane and Separation Technology, 5(3), 95–102. https://doi.org/10.6000/1929-6037.2016.05.03.2

Issue

Vol. 5 No. 3 (2016)

Section

Articles

License

Policy for Journals/Articles with Open Access

Authors who publish with this journal agree to the following terms:

  • Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.

  • Authors are permitted and encouraged to post links to their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work

Policy for Journals / Manuscript with Paid Access

Authors who publish with this journal agree to the following terms:

  • Publisher retain copyright .

  • Authors are permitted and encouraged to post links to their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work .
Crossref
Scopus
Google Scholar
Europe PMC