Fabrication of Hollow Microspheres Using Single Step Electrospraying Process

Authors

  • Praveen C. Ramamurthy Department of Materials Engineering, Indian Institute of Science, Bangalore, 560012, India
  • K. K. Khadija Department of Materials Engineering, Indian Institute of Science, Bangalore, 560012, India
  • K. Ranjith Department of Materials Engineering, Indian Institute of Science, Bangalore, 560012, India
  • Sumeet R. Mishra Department of Materials Engineering, Indian Institute of Science, Bangalore, 560012, India

DOI:

https://doi.org/10.6000/1929-5995.2014.03.02.5

Keywords:

Conducting polymers, Electrospraying, Hollow microspheres, PolyBenzoThiadiazole (PolyBT).

Abstract

In this study, a single step method for large scale fabrication of hollow microspheres with a narrow size distribution is presented. PolyBenzoThiadiazole (PolyBT), a conducting polymer, was electrosprayed at high voltage to obtain microspheres. Hollow spheres of size ranging from 4.1 to 7.3 µm were observed through scanning electron microscope images, without any chemical degradation as shown by FTIR studies. In addition, these microspheres demonstrated a change in optical and hydrophobic properties as exhibited by the UV-visible and contact angle measurements. Thus providing interesting opportunities for use in biomedical applications, sensors as well as optoelectronic devices.

References

Reyderman L, Stavchansky S. Electrostatic spraying. Int J Pharm 1995; 124: 75-85. http://dx.doi.org/10.1016/0378-5173(95)00078-W DOI: https://doi.org/10.1016/0378-5173(95)00078-W

Kumaraswamy S, Bergstedt T, Shi X, et al. Fluorescent. Proc Natl Acad Sci USA 2004; 101: 7511-5. http://dx.doi.org/10.1073/pnas.0402367101 DOI: https://doi.org/10.1073/pnas.0402367101

Méallet-Renault R, Denjean P, Pansu R. Polymer beads. Sens Actuators B Chem 1999; 59: 108-12. http://dx.doi.org/10.1016/S0925-4005(99)00205-1 DOI: https://doi.org/10.1016/S0925-4005(99)00205-1

Telting-Diaz M, Bakker E. Mass-Produced. Anal Chem 2002; 74: 5251-6. http://dx.doi.org/10.1021/ac025596i DOI: https://doi.org/10.1021/ac025596i

Déjugnat C, Sukhorukov GB. pH-Responsive. Langmuir 2004; 20: 7265-9. http://dx.doi.org/10.1021/la049706n DOI: https://doi.org/10.1021/la049706n

Fletcher RA, Brazin JA, Staymates ME, Benner Jr. BA, Gillen JG. Fabrication of polymer microsphere. Talanta 2008; 76: 949-55. http://dx.doi.org/10.1016/j.talanta.2008.04.066 DOI: https://doi.org/10.1016/j.talanta.2008.04.066

Ye N, Wygladacz K, Bakker E. Absorbance characterization. Anal Chim Acta 2007; 596: 195-200. http://dx.doi.org/10.1016/j.aca.2007.06.015 DOI: https://doi.org/10.1016/j.aca.2007.06.015

Zhao P, Yan M, Zhang C, Peng R, Ma D, Yu J. Determination of glyphosate. Spectrochim Acta A Mol Biomol Spectrosc 2011; 78: 1482-6. http://dx.doi.org/10.1016/j.saa.2011.01.037 DOI: https://doi.org/10.1016/j.saa.2011.01.037

Hwang SS, Cho CG, Kim H. Polymer microsphere. Electrochimica Acta 2010; 55: 3236-9. http://dx.doi.org/10.1016/j.electacta.2010.01.044 DOI: https://doi.org/10.1016/j.electacta.2010.01.044

Jang J, Ha J, Kim S. Fabrication of polyaniline. Macromol Res 2007; 15: 154-9. http://dx.doi.org/10.1007/BF03218767 DOI: https://doi.org/10.1007/BF03218767

Li L, Huang Y, Yan G, Liu F, Huang Z, Ma Z. Poly(3,4-ethylenedioxythiophene). Mater Lett 2009; 63: 8-10. http://dx.doi.org/10.1016/j.matlet.2008.08.016 DOI: https://doi.org/10.1016/j.matlet.2008.08.016

Sui J, Zhang L, Peng H, Travas-Sejdic J, Kilmartin PA. Self-assembly. Nanotechnology 2009 Oct 14; 20(41): 415606. http://dx.doi.org/10.1088/0957-4484/20/41/415606 DOI: https://doi.org/10.1088/0957-4484/20/41/415606

Liao Y, Li X-G, Kaner RB. Facile Synthesis. ACS Nano 2010; 4: 5193-202. http://dx.doi.org/10.1021/nn101378p DOI: https://doi.org/10.1021/nn101378p

Wang J, Wang J, Wang Z, Zhang F. A Template-Free. Macromol Rapid Commun 2009; 30: 604-8. http://dx.doi.org/10.1002/marc.200800726 DOI: https://doi.org/10.1002/marc.200800726

Hu Y, Jiang X, Ding Y, Chen Q, Yang CZ. Core-Template. Adv Mater 2004; 16: 933-7. http://dx.doi.org/10.1002/adma.200306579 DOI: https://doi.org/10.1002/adma.200306579

Gupta B, Chauhan DS, Prakash R. Controlled morphology. Mater Chem Phys 2010; 120: 625-30. http://dx.doi.org/10.1016/j.matchemphys.2009.12.026 DOI: https://doi.org/10.1016/j.matchemphys.2009.12.026

Atobe M, Ishikawa K, Asami R, Fuchigami T. Size-Controlled. Angew Chem Int Ed 2009; 48: 6069-72. http://dx.doi.org/10.1002/anie.200902062 DOI: https://doi.org/10.1002/anie.200902062

Liu H, Huang L, Huang Z, Qi G, Kei S, Yutaka H. Preparation of conducting poly N-methylaniline. J Wuhan Univ Technol-Mater Sci Ed 2008; 23: 536-40. http://dx.doi.org/10.1007/s11595-006-4536-6 DOI: https://doi.org/10.1007/s11595-006-4536-6

Sanada K, Patil R, Ooyama Y, Yano J, Harima Y. Template-free. Polym J 2006; 38: 732-6. http://dx.doi.org/10.1295/polymj.PJ2005222 DOI: https://doi.org/10.1295/polymj.PJ2005222

Wang Z, Wang Y, Hu N, Wei L, Chen S, Zhang Y. Polythiophene. J Polym Sci Part Polym Chem 2010; 48: 5265-9. http://dx.doi.org/10.1002/pola.24337 DOI: https://doi.org/10.1002/pola.24337

Meier W. Polymer nanocapsules. Chem Soc Rev 2000; 29: 295-303. http://dx.doi.org/10.1039/a809106d DOI: https://doi.org/10.1039/a809106d

Shenoy SL, Bates WD, Frisch HL, Wnek GE. Role of chain entanglements. Polymer 2005; 46: 3372-84. http://dx.doi.org/10.1016/j.polymer.2005.03.011 DOI: https://doi.org/10.1016/j.polymer.2005.03.011

Watanabe H, Matsuyama T, Yamamoto H. Experimental. J Electrost 2003; 57: 183-97. http://dx.doi.org/10.1016/S0304-3886(02)00139-0 DOI: https://doi.org/10.1016/S0304-3886(02)00139-0

Harpur IG, Bailey AG, Hashish AH. A design method. J Aerosol Sci 1996; 27: 987-96. http://dx.doi.org/10.1016/0021-8502(96)00044-4 DOI: https://doi.org/10.1016/0021-8502(96)00044-4

Bock N, Woodruff MA, Hutmacher DW, Dargaville TR. Electrospraying. Polymers 2011; 3: 131-49. http://dx.doi.org/10.3390/polym3010131 DOI: https://doi.org/10.3390/polym3010131

Nath SD, Son S, Sadiasa A, Min YK, Lee BT. Preparation. Int J Pharm 2013; Feb 25; 443: 87-94. http://dx.doi.org/10.1016/j.ijpharm.2012.12.037 DOI: https://doi.org/10.1016/j.ijpharm.2012.12.037

Hu C, Zhao J, Cui W. Fabrication. J Appl Polym Sci 2013; 128: 3177-83. http://dx.doi.org/10.1002/app.38383 DOI: https://doi.org/10.1002/app.38383

Zhang Q, Wang L, Wei Z, Wang X, Long S, Yang J. A new simple method. Colloid Polym Sci 2012; 290: 1257-63. http://dx.doi.org/10.1007/s00396-012-2645-7 DOI: https://doi.org/10.1007/s00396-012-2645-7

Liu Y, Wang C, Li M, Lai G, Shen Y. Synthesis and Spectroscopic. Macromolecules 2008; 41: 2045-8. http://dx.doi.org/10.1021/ma702035c DOI: https://doi.org/10.1021/ma702035c

Mancilha FS, DaSilveira Neto BA, Lopes AS, et al. Are Molecular. Eur J Org Chem 2006: 4924-33. http://dx.doi.org/10.1002/ejoc.200600376 DOI: https://doi.org/10.1002/ejoc.200600376

Jaworek A, Sobczyk AT. Electrospraying. J Electrost 2008; 66: 197-219. http://dx.doi.org/10.1016/j.elstat.2007.10.001 DOI: https://doi.org/10.1016/j.elstat.2007.10.001

Ranjith K, Swathi SK, Kumar P, Ramamurthy PC. Dithienylcyclopentadienone. Sol Energy Mater Sol Cells 2012; 98: 448-54. http://dx.doi.org/10.1016/j.solmat.2011.11.034 DOI: https://doi.org/10.1016/j.solmat.2011.11.034

Downloads

Published

2014-06-24

How to Cite

Ramamurthy, P. C., Khadija, K. K., Ranjith, K., & Mishra, S. R. (2014). Fabrication of Hollow Microspheres Using Single Step Electrospraying Process. Journal of Research Updates in Polymer Science, 3(2), 108–113. https://doi.org/10.6000/1929-5995.2014.03.02.5

Issue

Section

Articles