Characterization of Silane Modified Polyvinyl Acetate Water Based Dispersion Film
DOI:
https://doi.org/10.6000/1929-5995.2015.04.03.3Keywords:
Polyvinyl acetate, RAFT, alkoxysilane, siloxane bonds, element mappingAbstract
Major advantage of silane-modified systems is possibility to cross link reactive silanol groups and fortify polymer mechanical and chemical properties. However, application of modern analysis techniques and further characterization of macromolecular structure produced is complicated due to a poor solubility of silane modified polymer in various solvents. Silane modified polyvinyl acetate (PVAc) dispersions were produced by classic radical and RAFT polymerization using silane co-monomers and dispersion system stabilizer - silane modified industrial grade polyvinyl alcohol. The present paper deals with confirmation of silanol, siloxane bonds, silicon content and distribution, as well film surface morphology of silane modified PVAc dispersions films.
References
Yildirim Erbil H. Vinyl Acetate Emulsion Polymerization and Copolymerization with Acrylic Monomers. New York: CRC Press 2000. DOI: https://doi.org/10.1201/9781420038804
Shields J. Adhesive Handbook, 3rd Ed. London: Butterworths 1985.
Seidel A. Vinyl acetate Polymers, in Kirk-Othmer Encylopedia of Chemical Technology, 5th Ed. New York: Wiley 2007.
Tonnar J, Pouget E, Lacroix-Desmazers P, Boutevin B. Synthesis of poly(vinyl acetate)-b-poly(dimethylsiloxane-b-poly(vinyl acetate) triblock copolymers by iodine transfer polymerization. Eur Polym J 2008; 44 (2): 318-328. http://dx.doi.org/10.1016/j.eurpolymj.2007.11.026 DOI: https://doi.org/10.1016/j.eurpolymj.2007.11.026
Maynard DH. Synthesis of nanophase-segregated poly(vinyl acetate)-poly(dimethylsiloxane) and poly(vinyl acetate)-poly(styrene) graft copolymers. Polymer 2001; 42(18): 7567-7574. http://dx.doi.org/10.1016/S0032-3861(01)00230-0 DOI: https://doi.org/10.1016/S0032-3861(01)00230-0
Plesich MF, Zavaglia EA, inventor. Union carbide corp., assignee. Latex Polymers of Vinylacetate and a Silane. United States patent US 3729438. 1973.
Liu XH, Yi SP, Li HB, Huang C. Preparation of Poly(vinyl acetate) Modified by Triethoxyvinylsilane and Properties of Copolymeric Lattices. Iran Polym J 2007; 16(3): 207-213.
Naghash HJ, Mallakpour S, Mokhtarian N. Synthesis and characterization of silicone-modified vinyl acetate–acrylic emulsion copolymers. Prog Org Coat 2006; 55(4): 375-381. http://dx.doi.org/10.1016/j.porgcoat.2006.02.001 DOI: https://doi.org/10.1016/j.porgcoat.2006.02.001
Moriya T. inventor. Kuraray Co Ltd., assignee. Production of Vinyl Acetate – Based Polymer, Production of Saponified Vinyl Acetate-Based Polymer and Resin Composition. Japan patent JP 09071620. 1997.
Stark K, inventor. Wacker Polymers Systems GmbH & Co. KG., assignee. Silane-Modified Polyvinylacetals. United States patent US 6794477. 2004.
Petrie EM. Handbook of Adhesives and Sealants. New York: McGraw-Hill 2007.
Bengtsson M, Oksman K. The use of silane technology in crosslinking polyethylene/wood flour composites. Appl Sci Manu 2006; 37(5): 752-765. http://dx.doi.org/10.1016/j.compositesa.2005.06.014 DOI: https://doi.org/10.1016/j.compositesa.2005.06.014
Chrusciel JJ, Lesniak E. Modification of Thermoplastics with Reactive Silanes and Siloxanes. In Termoplastic Elastomers Ed. El-Sonbati A. 2012. [cited 2015 Oct 2]. Available from: http://cdn.intechopen.com/pdfs/34066/InTech-Modification_of_thermoplastics_with_reactive_silanes_and_siloxanes.pdf
Dubininkas M, Buika G. Dispersion production by semi-continuous radical vinyl acetate emulsion polymerization with silane co-monomer and characterization of final products. Chin J Polym Sci 2013; 31(2): 346-354. http://dx.doi.org/10.1007/s10118-013-1220-0 DOI: https://doi.org/10.1007/s10118-013-1220-0
Dubininkas M, Buika G, Minelga D. Impact of industrial Grade Modified PVA to Vinyl Acetate Semi-continuous Emulsion Polymerization and Properties of Final Product. Mater Sci Medz 2013; 19(1): 38-42. http://dx.doi.org/10.5755/j01.ms.19.1.3823 DOI: https://doi.org/10.5755/j01.ms.19.1.3823
Dubininkas M, Buika G. Production and characterization of 3- Methacryloxypropyltrimethoxysilane modified polyvinyl acetate dispersion. Kem Ind 2015. DOI: https://doi.org/10.15255/KUI.2014.034
Nyquist RA, Fiedler S, Streck R. Infrared study of vinylacetate, methyl acrylate and methyl methacyrlate in various solvents. Vib Spectrosc 1994; 6(3): 285-291. http://dx.doi.org/10.1016/0924-2031(93)E0064-9 DOI: https://doi.org/10.1016/0924-2031(93)E0064-9
Launer PJ. Infrared analysis of organosilicon compounds: Spectra-Structure correlations. Silicone compounds register and Review 1987; 100-103.
Abe Y, Honda Y, Gunii T. Preparation and Properties of Silicon-Containing Polymer hybrids from 3-Methacryloxypropyltrimethoxysilane. Appl Organomet Chem 1998; 12(10-11): 749-753. http://dx.doi.org/10.1002/(SICI)1099-0739(199810/11)12:10/11<749::AID-AOC782>3.0.CO;2-2 DOI: https://doi.org/10.1002/(SICI)1099-0739(199810/11)12:10/11<749::AID-AOC782>3.0.CO;2-2
Donescu D, Gosa K, Ciupitoiu A, Languri I. Semicontinuous Emulsion Polymerization of Vinyl Acetate. Part I. Homopolymerization with Poly-(Vinyl Alcohol) and Nonionic Coemulsifier. J Macromol Sci 1985; 22(5-7): 931-940. http://dx.doi.org/10.1080/00222338508056645 DOI: https://doi.org/10.1080/00222338508056645
Donescu D. Emulsion Polymerization of Vinyl Acetate. London: Applied Science Publishers 1981.
Brandrup J, Immergut EH, Grulke EA. Polymer Handbook. 4th Ed. New York: John Wiley & Sons 1999.
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