Effect of Acid-Hydrolyzed Thermoplastic Starch on the Mechanical, Thermal and Morphological Properties of Polyethylene Based Composites

Authors

  • Perla Mayari Trejo Ramí­rez Universidad Autónoma del Estado de Hidalgo. Ciudad del conocimiento, Área Académica de Químicas, ICBI–UAEH, Carretera Pachuca-Tulancingo Km 4.5, Col. Carboneras, Mineral de la Reforma, Hidalgo, C.P. 42184, Mexico
  • Ernesto Hernández-Hernández Centro de Investigación en Química Aplicada, Boulevard Enrique Reyna No. 140, Saltillo, Coah C.P. 25253, Mexico
  • Javier Castro Rosas Universidad Autónoma del Estado de Hidalgo. Ciudad del conocimiento, Área Académica de Químicas, ICBI–UAEH, Carretera Pachuca-Tulancingo Km 4.5, Col. Carboneras, Mineral de la Reforma, Hidalgo, C.P. 42184, Mexico
  • Silvia Guadalupe Solís-Rosales Centro de Investigación en Química Aplicada, Boulevard Enrique Reyna No. 140, Saltillo, Coah C.P. 25253, Mexico
  • José Roberto Villagómez-Ibarra Universidad Autónoma del Estado de Hidalgo. Ciudad del conocimiento, Área Académica de Químicas, ICBI–UAEH, Carretera Pachuca-Tulancingo Km 4.5, Col. Carboneras, Mineral de la Reforma, Hidalgo, C.P. 42184, Mexico
  • Carlos Alberto Gómez-Aldapa Universidad Autónoma del Estado de Hidalgo. Ciudad del conocimiento, Área Académica de Químicas, ICBI–UAEH, Carretera Pachuca-Tulancingo Km 4.5, Col. Carboneras, Mineral de la Reforma, Hidalgo, C.P. 42184, Mexico

DOI:

https://doi.org/10.6000/1929-5995.2015.04.04.4

Keywords:

Chemical modifications, LDPE, hydrolyzed thermoplastic starch.

Abstract

The effect of the addition of hydrolyzed thermoplastic maize starch on the physico mechanical properties of low-density polyethylene (LDPE)-based composites was studied. Acid-hydrolyzed native starch was thermoplasticized using 15 and 30% glycerol in weight relative to starch, after which the LDPE/thermoplastic starch (TPS) composites were prepared at TPS concentrations of 10, 25, and 50%. According to the results of Raman spectroscopy, the appearance of a new band at 756 cm-1 was observed, and it was attributed to the hydrolysis process and associated with the C-C-O vibrational modes of the glycosidic bond. The addition of both native and polyethylene hydrolyzed TPS reduced the Young’s modulus of the composites; but the reduction was greater for those containing native starch. Both the maximum stress and deformation decreased to a greater degree for the composites with hydrolyzed TPS. The composites containing TPS prepared with 15% glycerol exhibited a higher Young’s modulus compared to those with LDPE, although they exhibited fragile behavior. The degree of matrix crystallinity increased with the addition of TPS and showed the largest increase when TPS 50% hydrolyzed by weight was added, showing an increase of 35%. It was observed that the size of the TPS particles, both native and hydrolyzed, increased in size as the concentration of TPS in the matrix increased. The size of the hydrolyzed TPS particles was greater than that of the native TPS particles, and in the case the of the hydrolyzed TPS particles, some exhibited an ellipsoidal and/or fibrillar morphology.

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Published

2016-01-11

How to Cite

Ramí­rez, P. M. T., Hernández-Hernández, E., Rosas, J. C., Solís-Rosales, S. G., Villagómez-Ibarra, J. R., & Gómez-Aldapa, C. A. (2016). Effect of Acid-Hydrolyzed Thermoplastic Starch on the Mechanical, Thermal and Morphological Properties of Polyethylene Based Composites. Journal of Research Updates in Polymer Science, 4(4), 191–201. https://doi.org/10.6000/1929-5995.2015.04.04.4

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