Synthesis and Study of Electrical Properties of Di Ethylene Glycol Embedded ZrO2 Films as a Gas Sensor

Authors

  • Pravin Sadashiv More Department of Physics, Novel Material Characterization Laboratory, Government Institute of Science, Mumbai 400 032 (MS), India
  • Y. B. Khollam Department of Physics, Anantrao Pawar College, Pirangut, Tal.-Mulshi, Dist.-Pune, Pune 412 115 (MS), India
  • S. G. Gawande Department of Physics, Novel Material Characterization Laboratory, Government Institute of Science, Mumbai 400 032 (MS), India

DOI:

https://doi.org/10.6000/1929-5995.2012.01.02.2

Keywords:

DEG, Spray pyrolysis, LPG, Gas sensor, thin film

Abstract

In this paper, the effect of Di ethylene glycol (DEG) embedded zirconium dioxide (ZrO2) on microstructure and liquid petroleum gas (LPG) sensing characteristics of ZrO2 thin films prepared by spray pyrolysis method were investigated. The films are prepared at X wt. % concentrations (X = 1, 2, 3, 4 and 5) of DEG. Microstructure of ZrO2 thin film was drastically changed by the addition of DEG, indicating that the addition of DEG was effective to prevent the agglomeration of ZrO2 particles. The high material and phase purities are found from the characterization studies in all as-prepared films. The better sensitivity factor (SF) values SF ~102 (at T = 450C) and SF = 100 (at T = 37oC) are obtained at 1 wt. % and 5 wt. % of DEG respectively. It is observed that the gas sensing characteristics of these films are strongly influenced by the optimum concentration of DEG due to the high surface area of nano-sized ZrO2 particles.

References

Fuller MJ, Warwick ME. The catalytic oxidation of carbon monoxide on tin (iv) oxide. J Catal 1973; 29: 441-50. http://dx.doi.org/10.1016/0021-9517(73)90251-0 DOI: https://doi.org/10.1016/0021-9517(73)90251-0

Tatsuyama CH. Ichimuraand SH. Iwakuro H. Observation of GaSe–SnO2 heterostructure by XPS and AES. Jpn J Appl Phys 1982; 21: L25-L27. http://dx.doi.org/10.1143/JJAP.21.L25 DOI: https://doi.org/10.1143/JJAP.21.L25

Chaudhary VA, Mulla IS, Sainkar SR, Belhekar AA, Vijayamohanan K. Surface ruthenated tin oxide as a novel hydrocarbon sensor. Sensors & Actuators A 1988; 65: 197-202. http://dx.doi.org/10.1016/S0924-4247(97)01688-9 DOI: https://doi.org/10.1016/S0924-4247(97)01688-9

Duh JG, Jou JW, Chiou BS. Catalytic and gas sensing characteristics in Pd doped SnO2. J Electrochem Soc 1989; 136: 2740-47. http://dx.doi.org/10.1149/1.2097581 DOI: https://doi.org/10.1149/1.2097581

Ippommatsu M, Sasaki H, Yanagida H. Sensing mechanism of SnO2 gas sensors. J Mater Sci 1990; 25: 259-62. http://dx.doi.org/10.1007/BF00544217 DOI: https://doi.org/10.1007/BF00544217

Yamazoe N. New approaches for improving semiconductor gas sensors Sensors & Actuators B 1991; 5: 57-19. http://dx.doi.org/10.1016/0925-4005(91)80213-4 DOI: https://doi.org/10.1016/0925-4005(91)80213-4

Yamazoe N, Miura N. In: Yamauchi S, Ed. Chemical Sensor Technology, Kodansha/Elsevier, New York 1992; vol. 4: pp. 19-42. DOI: https://doi.org/10.1016/B978-0-444-98680-1.50007-3

Ruu AR, Seshdrj K, Rao CNR. Investigations of V2O5 based LPG sensors Talonto 1992; Vol. 39/11: pp. 1543-1547. DOI: https://doi.org/10.1016/0039-9140(92)80139-5

Orlik DR, Ivanovskaya MI, Kol KD. Characterization of semiconducting tin oxide films sensors prepared by sol–gel method. J Anal Chem 1995; 50: 1073-77.

Schweizer B, Berberich M, Zheng JG, Weimar U, Goepel W, Barsan N, et al. The effect of Pt and Pd doping on the response of nanocrystalline SnO2 gas sensors to CO, Sensors & Actuators B 1996; 31: 71-75. http://dx.doi.org/10.1016/0925-4005(96)80018-9 DOI: https://doi.org/10.1016/0925-4005(96)80018-9

Chaudhary VA, Mulla IS, Vijayamohanan K. Synergistic sensitivity effects in surface modified tin oxide using Ru–Pd oxides. J Mater Sci Lett 1997; 16: 1819-21. http://dx.doi.org/10.1023/A:1018568702315 DOI: https://doi.org/10.1023/A:1018568702315

Shimizu Y. Development of high performance semiconductor gas sensors by micro- and macro-structural design. Chem Sensors 2002; 18: 42-54.

Shoyama M, Hashimoto N. Effect of poly ethylene glycol addition on the microstructure and sensor characteristics of SnO2 thin films prepared by sol–gel method. Sensors & Actuators B 2003; 93: 585-89. http://dx.doi.org/10.1016/S0925-4005(03)00215-6 DOI: https://doi.org/10.1016/S0925-4005(03)00215-6

Downloads

Published

2013-01-10

How to Cite

More, P. S., Khollam, Y. B., & Gawande, S. G. (2013). Synthesis and Study of Electrical Properties of Di Ethylene Glycol Embedded ZrO2 Films as a Gas Sensor . Journal of Research Updates in Polymer Science, 1(2), 72–74. https://doi.org/10.6000/1929-5995.2012.01.02.2

Issue

Section

Articles