Solvent Isotope Effect on Hydrogen-Transfer Reduction of CO2 into Formate with Glycerine by Alkaline Hydrothermal Reaction

Authors

  • Zheng Shen State Key Laboratory of Catalysis Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
  • Minyan Gu National Engineering Research Center of Facilities Agriculture, State Key Laboratory of Pollution Control and Resources Reuse, Tongji University, Shanghai 200092, China
  • Long Yang National Engineering Research Center of Facilities Agriculture, State Key Laboratory of Pollution Control and Resources Reuse, Tongji University, Shanghai 200092, China
  • Shiyang Liu National Engineering Research Center of Facilities Agriculture, State Key Laboratory of Pollution Control and Resources Reuse, Tongji University, Shanghai 200092, China
  • Wei Zhang National Engineering Research Center of Facilities Agriculture, State Key Laboratory of Pollution Control and Resources Reuse, Tongji University, Shanghai 200092, China
  • Wenjie Dong National Engineering Research Center of Facilities Agriculture, State Key Laboratory of Pollution Control and Resources Reuse, Tongji University, Shanghai 200092, China

DOI:

https://doi.org/10.6000/1929-6002.2015.04.01.3

Keywords:

CO2, glycerine, solvent isotope effect, alkaline hydrothermal reaction.

Abstract

To examine the solvent isotope effect on hydrogen-transfer reduction of CO2 into formate with glycerine by alkaline hydrothermal reaction, intermediates were identified by 13C-NMR, 1H-NMR, 2H-NMR, LC-MS analyses. The results showed that (1) CO2 was indeed converted into abiogenic formate; (2) a ketone carbonyl group as intermediate product was formed on hydrogen-transfer reduction of CO2 into formate with glycerine by alkaline hydrothermal reaction; (3) acetol was the most probable intermediate in the first reaction by undergoing a dehydration rather than a dehydrogenation.

References

Arakawa H, Aresta M, Armor JN. Catalysis research of relevance to carbon management: Progress, challenges, and opportunities. Chem Rev 2001; 101: 953-96.http://dx.doi.org/10.1021/cr000018s

Sakakura T, Choi JC, Yasuda H. Transformation of carbon dioxide. Chem Rev 2007; 107: 2365-87.http://dx.doi.org/10.1021/cr068357u

Chheda JN, Huber GW, Dumesic JA. Liquid-phase catalytic processing of biomass-derived oxygenated hydrocarbons to fuels and chemicals. Angew Chem Int Ed 2007; 46: 7164-83.http://dx.doi.org/10.1002/anie.200604274

Corma A, Iborra S, Velty A. Chemical routes for the transformation of biomass into chemicals Chem Rev 2007; 107: 2411-502. http://dx.doi.org/10.1021/cr050989d

Shen Z, Zhang YL, Jin FM. The alcohol-mediated reduction of CO2 and NaHCO3 into formate: a hydrogen transfer reduction of NaHCO3 with glycerine under alkaline hydrothermal conditions. RSC Adv 2012; 2: 797-801. http://dx.doi.org/10.1039/c1ra00886b

Mok WS, Antal MJ. Formation of acrylic-acid from lactic-acid in supercritical water. J Org Chem 1989; 54: 4596-602. http://dx.doi.org/10.1021/jo00280a027

Kuhlmann B, Arnett EM, Siskin M. Classical Organic Reactions in Pure Superheated Water. J Org Chem 1994: 59: 3098-101. http://dx.doi.org/10.1021/jo00090a030

Kuhlmann B, Arnett EM, Siskin MJ. H-D Exchange in Pinacolone by Deuterium Oxide at High Temperature and Pressure. Org Chem 1994; 59: 5377-80. http://dx.doi.org/10.1021/jo00097a046

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Published

2015-03-11

How to Cite

Shen, Z., Gu, M., Yang, L., Liu, S., Zhang, W., & Dong, W. (2015). Solvent Isotope Effect on Hydrogen-Transfer Reduction of CO2 into Formate with Glycerine by Alkaline Hydrothermal Reaction. Journal of Technology Innovations in Renewable Energy, 4(1), 21–24. https://doi.org/10.6000/1929-6002.2015.04.01.3

Issue

Vol. 4 No. 1 (2015)

Section

Articles

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Copyright (c) 2015 Journal of Technology Innovations in Renewable Energy

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