Refractive Properties of Binary Mixtures Formed by an Isomer of Chlorobutane and Butyl Ethyl Ether

Authors

  • Diego F. Montaño Universidad de Antioquia
  • Héctor Artigas Ciudad Universitaria
  • M. Carmen López Ciudad Universitaria
  • Carlos Lafuente Ciudad Universitaria

DOI:

https://doi.org/10.6000/1929-5030.2014.03.02.3

Keywords:

Butyl ethyl ether, Isomeric chlorobutane, Predicted properties, Refractive index.

Abstract

Refractive indices of the binary mixtures containing an isomer of chlorobutane (1-chlorobutane, 2-chlorobutane, 2-methyl-1-chloropropane, or 2-methyl-2-chloropropane) and butyl ethyl ether have been measured at seven temperatures from T = 283.15 to 313.15 K From these data refractive index deviations were calculated and correlated with a Redlich-Kister polynomial expansion. The refractive index deviations were found positive. Finally, from these refractive indices both densities and surface tensions of the studied systems were predicted and compared with previously reported values.

References


[1] Mendonça AFSS, Dias SMA, Dias FA, Barata BAS, Lampreia IMS. Temperature dependence of thermodynamic properties of leucyl-glycine aqueous solutions from 15 to 45 degrees C. Fluid Phase Equilib 2003; 212: 67-79. http://dx.doi.org/10.1016/S0378-3812(03)00264-4
[2] Soto A, Arce A, Khoshkbarchi MK. Thermodynamics of diglycine and triglycine in aqueous NaCl solutions: Apparent molar volume, isentropic compressibility, and refractive index. J Solution Chem 2004; 33: 11-21. http://dx.doi.org/10.1023/B:JOSL.0000026642.07518.43
[3] Brocos P, Piñeiro A, Bravo R, Amigo A, Roux AH, RouxDesgranges G. Thermodynamics of mixtures involving some linear or cyclic ketones and cyclic ethers. 4. Systems containing 1,3-dioxolane. J Chem Eng Data 2004; 49: 647- 57. http://dx.doi.org/10.1021/je034223r
[4] Kamble SP, Undre PB, SudakeYS, Maharolkar AP, Khirade PW. Study of refractive index, density, molar volume and their excess properties of binary systems. Asian J Chem 2012; 24: 5731-5.
[5] Montaño D, Gascón I, Schmid B, Gmehling J, Lafuente C. Experimental and predicted properties of the binary mixtures containing an isomeric chlorobutane and butyl ethyl ether. J Chem Thermodyn 2012; 51: 150-8. http://dx.doi.org/10.1016/j.jct.2012.02.039
[6] Montaño D, Giner B, Martín S, Lafuente C. Surface study of binary mixtures containing chlorinated and oxygenated compounds. J Mol Liq 2013; 181: 1-7. http://dx.doi.org/10.1016/j.molliq.2013.01.024
[7] Chen H-W, Wen C-C, Tu C-H. Excess molar volumes, viscosities, and refractive indexes for binary mixtures of 1- chlorobutane with four alcohols at T = (288.15, 298.15, and 308.15) K. J Chem Eng Data 2004; 49: 347-51. http://dx.doi.org/10.1021/je030226s
[8] Verma N, Maken S, Singh KC. Volumetric properties of secand tert-butyl chloride with benzene, toluene and xylenes at 308.15 K. J Mol Liq 2008; 141: 35-8. http://dx.doi.org/10.1016/j.molliq.2008.02.008
[9] Riddick JA, Bunger WB, Sakano TK. Organic Solvents, Physical Properties and Methods of Purification (Techniques of Chemistry), 4th ed. New York: Wiley-Interscience 1986.
[10] Fialkov YY, Fenerly GN. Molar additive properties in physicochemical analysis of binary liquid mixtures. Russ J Inorg Chem 1964; 9: 1205-13.
[11] Fialkov YY. Molar-additive properties in physicochemical analysis of binary liquid systems. Russ J Phys Chem 1967; 41: 398-93.
[12] Redlich O, Kister AT. Algebraic representation of thermodynamic properties and the classification of solutions. Ind Eng Chem 1948; 40: 345-8. http://dx.doi.org/10.1021/ie50458a036
[13] Brocos P, Piñeiro A, Bravo R, Amigo A. Refractive indices, molar volumes and molar refractions of binary liquid mixtures: concepts and correlations. Phys Chem Chem Phys 2003; 5: 550-7. http://dx.doi.org/10.1039/b208765k
[14] Nakata M, Sakurai M. Refractive-index and excess volume for binary liquid mixtures. 1. Analyses of new and old data for binary mixtures. J Chem Soc Faraday Trans 1 1987; 83:2449-57. http://dx.doi.org/10.1039/f19878302449
[15] Gladstone JF, Dale TP. Researches on the refraction, dispersion, and sensitiveness of liquids. Phylos Trans R Soc London 1863; 153: 317-43. http://dx.doi.org/10.1098/rstl.1863.0014
[16] Acevedo IL, Pedrosa GC, Katz M. Relationship between surface tension and refractive index in binary nonelectrolyte mixtures. An Asoc Quim Argent 1990; 78: 161-7.
[17] Piñeiro A, Brocos P, Amigo A, Pintos M, Bravo R. Prediction of excess volumes and excess surface tensions from experimental refractive indices. Phys Chem Liq 2000; 38: 251-60. http://dx.doi.org/10.1080/00319100008030275
[18] Sugden S. A relation between surface tension, density, and chemical composition. J Chem Soc 1924; 125:1177-81. http://dx.doi.org/10.1039/ct9242501177
[19] McNaught D, Wilkinson A. IUPAC Compendium of Chemical Terminology, 2nd ed. Oxford: Blackwell Science 1997.

Published

2014-06-02

How to Cite

Montaño, D. F., Artigas, H., López, M. C., & Lafuente, C. (2014). Refractive Properties of Binary Mixtures Formed by an Isomer of Chlorobutane and Butyl Ethyl Ether. Journal of Applied Solution Chemistry and Modeling, 3(2), 58–64. https://doi.org/10.6000/1929-5030.2014.03.02.3

Issue

Section

General Articles