Study of Molecular Interactions in Binary Mixtures of Diethyl Carbonate + Benzene Derivatives at Different Temperatures
DOI:
https://doi.org/10.6000/1929-5030.2015.04.02.4Keywords:
Ultrasonic velocity, density, molecular interactions, binary mixtures, diethyl carbonateAbstract
Investigation on the molecular interactions between binary mixtures containing diethyl carbonate in combination with nitrobenzene, chlorobenzene and aniline is presented. Ultrasonic velocity and density values were determined for the individual components as well as binary mixtures of the above benzene derivatives with diethyl carbonate at temperatures (293.15, 298.15, 303.15, 308.15, 313.15, 318.15 and 323.15) K over the entire composition range. Further, adiabatic compressibility and acoustic impedance values were calculated using the experimental results. In addition to these parameters, the excess parameters like excess adiabatic compressibility, excess acoustic impedance and deviation in ultrasonic velocity were also obtained. Based on all these results, molecular interactions among the selected components were discussed.
References
[1] Singh A, Saxena SK, Saxena MC. Dielectric relaxation in OH-O bond complexes. Phys Chem Liq 1983; 12: 329-336. http://dx.doi.org/10.1080/00319108308084562
[2] Pandey JD, Soni NK, Dey R, Verma R. Excess functions of binary mixtures at varying pressures. Fluid Phase Equilib 2004; 215: 17-22. http://dx.doi.org/10.1016/j.fluid.2003.06.004
[3] Shukla D, Singh S, Parveen S, Gupta M, Shukla JP. Thermodynamical properties of binary mixtures of methanol with chlorobenzene and bromobenzene from 293 K to 313 K. Int J Thermophys 2008; 29: 1376-84. http://dx.doi.org/10.1007/s10765-008-0444-7
[4] Shukla RK, Shukla SK, Pandey VK, Awasthi P. Sound velocity, effective temperature and pseudo-Gruneisen parameters of Pb-Sn mixtures at elevated temperatures. J Phys Chem Liq 2007; 45: 169-80. http://dx.doi.org/10.1080/00319100601126794
[5] Sudhamsa B, SarathBabu M, Narendra K. Study on thermodynamic properties of binary mixtures of diethyl carbonate with benzonitrile, benzaldehyde at different temperatures. Int Lett Chem Phys Astron 2014; 19: 1-7. http://dx.doi.org/10.18052/www.scipress.com/ILCPA.38.1
[6] Gayol A, Ladia MC, Alfonsina EA, Raquel EM, Jose LL. Volumetric properties of (dialkyl carbonate +n-alkane) mixtures at high pressures: experimental measurement and Nitta-Chao model prediction. J Chem Thermodyn 2013; 58: 245-53. http://dx.doi.org/10.1016/j.jct.2012.11.011
[7] Balasaheb RA, Machhindra KL, Nilesh NW, Dnyaneshwar SW. Viscosities, ultrasonic velocities at (288.15 and 298.15) K, and refractive indices at (298.15) K of binary mixtures of 2,4,6-trimethyl-1,3,5-trooxane with dimethyl carbonate, diethyl carbonate and propylene carbonate. J Chem Eng Data 2006; 51: 68-72. http://dx.doi.org/10.1021/je050183a
[8] Ratnam MV, Sudhir M, Nandini M. Excess properties of diethyl carbonate + ketone binary mixtures at variable temperatures: Application of PFP theory to excess volumes. J Mol Liq 2013; 177: 229-36. http://dx.doi.org/10.1016/j.molliq.2012.10.038
[9] Joshi SS, Aminabhavi TM, Ramachandra HB, Shukla SS. Densities and viscosities of binary liquid mixtures of nitrobenzene with cyclohexane and N,N-dimethylformamide. J Chem Eng Data 1990; 35: 185-7. http://dx.doi.org/10.1021/je00060a027
[10] Thirumaran S, Savithri S. Ultrasonic investigation in ternary liquid mixtures of substituted benzenes with acetophenone at different temperatures. J Ind Chem Soc 2010; 87: 279-87.
[11] Ali A, Tariq M. Thermodynamic and transport behavior of binary liquid mixtures of benzyl alcohol with monocyclic aromatics at 303.15 K. J Mol Liq 2006; 128: 50-5. http://dx.doi.org/10.1016/j.molliq.2005.09.002
[12] Alonso I, Mozo I, De La Fuente IG, Gonzalez JA, Cobos JC. Thermodynamics of ketone + amine mixtures Part V. Volumetric and speed of sound data at (293.15, 298.15 and 303.15) K for mixtures of 2-Heptanone with aniline, NMethylaniline or Pyridine. J Solution Chem 2011; 40: 2057- 71. http://dx.doi.org/10.1007/s10953-011-9774-3
[13] Redlich O, Kister AT. Algebraic representation of thermodynamic properties and the classification of solutions. Ind Eng Chem 1948; 40: 345-8. http://dx.doi.org/10.1021/ie50458a036
[14] Kiyohara O, Grolier J-PE, Benson GC. Excess volumes, ultrasonic velocities, and adiabatic compressibilities for binary cycloalkanol mixtures at 25° C. Can J Chem 1974; 52: 2287-93. http://dx.doi.org/10.1139/v74-330
[15] Fort RJ, Moore WR. Adiabatic compressibilities of binary liquid mixtures. Trans Faraday Soc 1965; 61: 2102-11. http://dx.doi.org/10.1039/tf9656102102
[16] Narendra K, Srinivasu Ch, Fakruddin SK, Narayanamurthy P. Excess parameters of binary mixtures of anisaldehyde with o-cresol, m-cresol and p-cresol at T = (303.15, 308.15, 313.15 and 318.15) K. J Chem Thermodyn 2011; 43: 1604- 11. http://dx.doi.org/10.1016/j.jct.2011.05.018
[17] Nath G, Sahu S, Paikaray R. Study of acoustic parameters of binary mixtures of a non-polar liquid with polar liquid at different frequencies. Indian J Phys 2009; 83: 429-36. http://dx.doi.org/10.1007/s12648-009-0024-0
[18] Reddy Y, Naidu PS, Prasad KR. Ultrasonic study of acetophenones in the binary-mixtures containing isopropanol as common component. Indian J Pure Appl Phys 1994; 32: 958-63.
Downloads
Published
2015-06-16
How to Cite
Narendra, K., Sudhamsa, B., Babu, M. S., & Krishna, T. (2015). Study of Molecular Interactions in Binary Mixtures of Diethyl Carbonate + Benzene Derivatives at Different Temperatures. Journal of Applied Solution Chemistry and Modeling, 4(2), 119–127. https://doi.org/10.6000/1929-5030.2015.04.02.4
Issue
Section
General Articles
License
Policy for Journals/Articles with Open Access
Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
- Authors are permitted and encouraged to post links to their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work
Policy for Journals / Manuscript with Paid Access
Authors who publish with this journal agree to the following terms:
- Publisher retain copyright .
- Authors are permitted and encouraged to post links to their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work .
