Adsorption of Rare Earth Elements (REEs) onto Activated Carbon Modified with Potassium Permanganate (KMnO4)

Authors

  • Naoki Kano Department of Chemistry and Chemical Engineering, Faculty of Engineering, Niigata University,
  • Meiling Pang Graduate School of Science and Technology, Niigata University
  • Yanling Deng Graduate School of Science and Technology, Niigata University
  • Hiroshi Imaizumi Department of Chemistry and Chemical Engineering, Faculty of Engineering, Niigata University

DOI:

https://doi.org/10.6000/1929-5030.2017.06.02.1

Keywords:

Adsorption, modified activated carbon, rare earth elements (REEs), adsorption isotherms, kinetics

Abstract

The adsorption capacity of activated carbon modified with potassium permanganate (KMnO4) for rare earth elements (REEs) from aqueous solution was investigated. The modified activated carbon was characterized by SEM (scanning electron microscopy), FT-IR (Fourier transform infrared spectrometer), and N2 adsorption-desorption tests. Adsorption experiments from aqueous solutions containing known amounts of some REEs (i.e. La, Lu, Yb, Eu, Y, Sc) onto the carbon were explored in a batch system. The amount of REEs adsorbed at different pH values, initial concentrations, and contact times were determined by inductively coupled plasma-atomic emission spectrometry (ICP-AES) in order to determine the optimum conditions for REEs adsorption. The adsorption of REEs on the activated carbon was well fitted by the Langmuir isothermal adsorption equation. The rates of adsorption were found to conform to pseudo-second order kinetic. These results present the modified activated carbon as an efficient adsorbent for REEs, hence creating new avenues for the treatment of industrial waste waters including pollutants. It is very significant information from the viewpoint of environmental protection.

References


[1] Bauer D, Diamond D, Li J, Sandalow D, Telleen P, Wanner B. US Department of Energy Critical Materials Strategy. U.S. Department of Energy Critical Materials Strategy, United States 2010. https://doi.org/10.2172/1000846
[2] Smith YR, Bhattacharyya D, Willhard T, Misra M. Adsorption of aqueous rare earth elements using carbon black derived from recycled tires. Chem Eng J 2016; 296: 102-111. https://doi.org/10.1016/j.cej.2016.03.082
[3] Peng G, Tian G, Liu J, Bao Q, Zang L. Removal of heavy metals from sewage sludge with a combination of bioleaching and electrokinetic remediation technology. Desalination 2011; 271: 100-104. https://doi.org/10.1016/j.desal.2010.12.015
[4] Sag Y, Kutsal T. Determination of the biosorption heats of heavy metal ions on Zoogloea ramigera and Rhizopus arrhizus. Biochem Eng J 2000; 6: 145-151. https://doi.org/10.1016/S1369-703X(00)00083-8
[5] Bahramifar N, Yamini Y. On-line preconcentration of some rare earth elements in water samples using C 18-cartridge modified with l-(2-pyridylazo) 2-naphtol (PAN) prior to simultaneous determination by inductively coupled plasma optical emission spectrometry (ICP–OES). Analytica Chimica Acta 2005; 540: 325-332. https://doi.org/10.1016/j.aca.2005.03.058
[6] He M, Hu B, Zeng Y, Jiang Z. ICP-MS direct determination of trace amounts of rare earth impurities in various rare earth oxides with only one standard series. J Alloy Compd 2005; 390: 168-174. https://doi.org/10.1016/j.jallcom.2004.06.107
[7] Yesiller SU, Eroglu AE, Shahwan T. Removal of aqueous rare earth elements (REEs) using nano-iron based materials. J Ind Eng Chem Res 2013; 19: 898-907. https://doi.org/10.1016/j.jiec.2012.11.005
[8] Davranche M, Pourret O, Gruau G, Dia A. Impact of humate complexation on the adsorption of REE onto Fe oxyhydroxide. J Colloid Interf Sci 2004; 277: 271-279. https://doi.org/10.1016/j.jcis.2004.04.007
[9] Wan Y, Liu C. The effect of humic acid on the adsorption of REEs on kaolin. Colloids and Surfaces A: Physicochem. Eng Aspects 2006; 290: 112-117. https://doi.org/10.1016/j.colsurfa.2006.05.010
[10] Sanematsu K, Kon Y, Imai A. Influence of phosphate on mobility and adsorption of REEs during weathering of granites in Thailand. J Asian Earth Sci 2015; 111: 14-30. https://doi.org/10.1016/j.jseaes.2015.05.018
[11] Ding SM, Liang T, Zhang CS, Huang ZC, Xie YN, Chen TB. Fractionation Mechanisms of Rare Earth Elements (REEs) in Hydroponic Wheat: An Application for Metal Accumulation by Plants. Environ Sci Technol 2006; 40: 2686-2691. https://doi.org/10.1021/es052091b
[12] Suat U, Murat E, Turgay T, Selhan K. Removal of lead (II) and nickel (II) ions from aqueous solution using activated carbon prepared from rapeseed oil cake by Na2CO3 activation. Clean Tech Environ Policy 2015; 17: 747-756. https://doi.org/10.1007/s10098-014-0830-8
[13] Peric J, Trgo M, Medvidovic NV. Removal of zinc, copper and lead by natural zeolite-a comparison of adsorption isotherms. Water Research 2004; 38: 1893-1899. https://doi.org/10.1016/j.watres.2003.12.035
[14] Mobasherpour I, Salahi E, Ebrahimi M. Removal of divalent nickel cations from aqueous solution by multi-walled carbon nano tubes: equilibrium and kinetic processes. Res Chem Intermed 2012; 38: 2205-2222. https://doi.org/10.1007/s11164-012-0537-6
[15] Wang JL, Chen C. Biosorbents for heavy metals removal and their future. Biotechnol Adv 2009; 27: 195-226. https://doi.org/10.1016/j.biotechadv.2008.11.002
[16] Haider S, Bukhari N, Park SY, Iqbal Y, Masry WA. Adsorption of bromo-phenol blue from an aqueous solution onto thermally modified granular charcoal. Chem Eng Res Des 2011; 89: 23-28. https://doi.org/10.1016/j.cherd.2010.04.022
[17] Sun YB, Yang ST, Sheng GD, Guo ZQ, Wang XK. The removal of U(VI) from aqueous solution by oxidized multiwalled carbon nanotubes. J Environ Radioact 2012; 105: 40-47. https://doi.org/10.1016/j.jenvrad.2011.10.009
[18] Tuzun I, Bayramoglu G, Yalcin E, Basaran G, Celik G, Anca MY. Equilibrium and kinetic studies on biosorption of Hg(II), Cd(II) and Pb(II) ions onto microalgae Chlamydomonas reinhardtii. J Environ Manage 2005; 77: 85-92. https://doi.org/10.1016/j.jenvman.2005.01.028
[19] Ricordel S, Taha S, Cisse I, Dorange G. Heavy metals removal by adsorption onto peanut husks carbon: characterization, kinetic study and modeling. Sep Purif Technol 2001; 24: 389-401. https://doi.org/10.1016/S1383-5866(01)00139-3
[20] Dilek D, Andrzej WT, Ulker B. Kinetics and thermodynamics of hexavalent chromium adsorption onto activated carbon derived from acrylonitrile-divinylbenzene copolymer. Chem Eng J 2012; 187: 193-202. https://doi.org/10.1016/j.cej.2012.01.120
[21] Kobya M, Demirbas E, Senturk E, Lnce M. Adsorption of heavy metal ions from aqueous solutions by activated carbon prepared from apricot stone. Bioresour Technol 2005; 96: 1518-1521. https://doi.org/10.1016/j.biortech.2004.12.005
[22] Li YH, Di Z, Ding J, Wu D, Luan Z, Zhu Y. Adsorption thermodynamics, kinetic and desorption studies of Pb2+ on carbon nanotubes. Water Res 2005; 39: 605-609. https://doi.org/10.1016/j.watres.2004.11.004
[23] Rao GP, Lu C, Su F. Sorption of divalent metal ions from aqueous solution by carbon nanotubes: a review. Sep Purif Technol 2007; 58: 224-231. https://doi.org/10.1016/j.seppur.2006.12.006
[24] Li YH, Wang SG, Luan ZK, Ding J, Xu CL. Adsorption of cadmium(II) from aqueous solution by surface oxidized carbon nanotubes. Carbon 2003; 41: 1057-1062. https://doi.org/10.1016/S0008-6223(02)00440-2
[25] Shan XM, Zhu SQ, Zhang WH. Effect of surface modification of activated carbon on its adsorption capacity for NH3. J China Univ Mining Technol 2008; 18: 0261-0265. https://doi.org/10.1016/S1006-1266(08)60055-3
[26] Rasheed A, Howe JY, Dadmun MD, Britt PF. The efficiency of the oxidation of carbon nanofibers with various oxidizing agents. Carbon 2007; 45: 1072-1080. https://doi.org/10.1016/j.carbon.2006.12.010
[27] Lu C, Chiu H. Chemical modification of multiwalled carbon nanotubes for sorption of Zn2+ from aqueous solution. Chem Eng J 2008; 139(3): 462-468. https://doi.org/10.1016/j.cej.2007.08.013
[28] Mourão PAM, Laginhas C, Custódio F, Nabais JMV, Carrott PJM, Ribeiro Carrott MML. Influence of oxidation process on the adsorption capacity of activated carbons from lignocellulosic precursors. Fuel Process Ttechnol 2011; 92(2): 241-246. https://doi.org/10.1016/j.fuproc.2010.04.013
[29] Daifullah AAM, Yakout SM, Elreefy SA. Adsorption of fluoride in aqueous solutions using KMnO4 - modified activated carbon derived from steam pyrolysis of rice straw. J Hazard Mater 2007; 147: 633-643. https://doi.org/10.1016/j.jhazmat.2007.01.062
[30] Fual G, Hakan Y, Giray T. Determination of kinetic and equilibrium parameters of the batch adsorption of Mn(II), Co(II), Ni(II) and Cu(II) from aqueous solution by black carrot (Daucus carota L.) residues. J Hazard Mater 2008; 153: 1275-1287. https://doi.org/10.1016/j.jhazmat.2007.09.087
[31] Muhammad A, Shafaqat A, Muhammad R, Muhammad Z, Muhammad I, Farhat A, et al. Mechanisms of siliconmediated alleviation of heavy metal toxicity in plants: a review. Ecotoxicol Environ Saf 2015; 119: 186-197. https://doi.org/10.1016/j.ecoenv.2015.05.011
[32] Dhaouadi A, Monser L, Adhoum N. Removal of rotenone insecticide by adsorption onto chemically modified activated carbons. J Hazard Mater 2010; 181: 692-699. https://doi.org/10.1016/j.jhazmat.2010.05.068
[33] Sarin V, Pant KK. Removal of chromium from industrial waste by using eucalyptus bark. Bioresour Technol 2006; 97: 15-20. https://doi.org/10.1016/j.biortech.2005.02.010
[34] Durano?lu D, Trochimczuk AW, Beker U. Kinetics and thermodynamics of hexavalent chromium adsorption onto activated carbon derived from acrylonitrile–divinylbenzene copolymer. Chem Eng J 2012; 187: 193-202. https://doi.org/10.1016/j.cej.2012.01.120
[35] Hall KR, Eagleton LC, Acrivos A, Vermeulen T. Pore and solid-diffusion kinetics in fixed-bed adsorption under constant-pattern conditions. Ind Eng Chem Res 1966; 5: 213-223. https://doi.org/10.1021/i160018a011
[36] Rahmati MM, Rabbani P, Abdolali A, Keshtkar AR. Kinetics and equilibrium studies on biosorption of cadmium, lead, and nickel ions from aqueous solutions by intact and chemically modified brown algae. J Hazard Mater 2011; 185: 401-407. https://doi.org/10.1016/j.jhazmat.2010.09.047
[37] Pillai SS, Mullassery MD, Fernandez NB, Girija N, Geetha P, Koshy M. Biosorption of Cr(VI) from aqueous solution by chemically modified potato starch: Equilibrium and kinetic studies. Ecotox Environ Safe 2013; 92: 199-205. https://doi.org/10.1016/j.ecoenv.2013.01.020
[38] Zhu JZ, Yang J, Deng BL. Ethylenediamine modified Activated Carbon for Aqueous Lead Adsorption, Environ. Chem Lett 2010; 8: 277-282. https://doi.org/10.1007/s10311-009-0217-y
[39] Chingombe P, Saha B, Wakeman RJ. Surface modification and characterisation of a coal-based activated carbon. Carbon 2005; 43: 3132-3143. https://doi.org/10.1016/j.carbon.2005.06.021
[40] Dolatyari L, Yaftian MR, Rostamnia S. Adsorption characteristics of Eu(III) and Th(IV) ions onto modified mesoporous silica SBA-15 materials. J Taiwan Inst Chem Engrs 2016; 60: 174-184. https://doi.org/10.1016/j.jtice.2015.11.004
[41] Liu YH, Li Q, Cao XH, Wang YQ, Jiang XH, Li M, et al. Removal of uranium(VI) from aqueous solutions by CMK-3 and its polymer composite. Appl Surf Sci 2013; 285: 258- 266. https://doi.org/10.1016/j.apsusc.2013.08.048
[42] Gerente C, Lee VKC, Cloirec PL, Mckay G. Application of chitosan for the removal of metals from wastewaters by adsorption-Mechanisms and models review. Crit Rev Env Sci Tec 2007; 37: 41-127. https://doi.org/10.1080/10643380600729089
[43] Abbasizadeh S, Keshtkar AR, Mousavian MA. Preparation of a novel electrospun polyvinyl alcohol/titanium oxide nanofiber adsorbent modified with mercapto groups for uranium(VI) and thorium(IV) removal from aqueous solution. Chem Eng J 2013; 220: 161-171. https://doi.org/10.1016/j.cej.2013.01.029
[44] Smith YR, Bhattacharyya D, Willhard T, Misra M. Adsorption of aqueous rare earth elements using carbon black derived from recycled tires. Chem Eng J 2016; 296: 102-111. https://doi.org/10.1016/j.cej.2016.03.082
[45] Chen L, Bai B. Equilibrium, kinetic, thermodynamic, and in situ regeneration studies about methylene blue adsorption by the raspberry-like TiO2 yeast microspheres. Ind. Eng Chem Res 2013; 52: 15568-15577. https://doi.org/10.1021/ie4020364
[46] Fu JW, Chen ZH, Wang MH, Liu SJ, Zhang JH, Zhang JN, et al. Adsorption of methylene blue by a high-efficiency adsorbent (polydopamine microspheres): kinetics, isotherm, thermodynamics and mechanism analysis. Chem Eng J 2015; 259(1): 53-61. https://doi.org/10.1016/j.cej.2014.07.101

Downloads

Published

2017-06-17

How to Cite

Kano, N., Pang, M., Deng, Y., & Imaizumi, H. (2017). Adsorption of Rare Earth Elements (REEs) onto Activated Carbon Modified with Potassium Permanganate (KMnO4). Journal of Applied Solution Chemistry and Modeling, 6(2), 51–61. https://doi.org/10.6000/1929-5030.2017.06.02.1

Issue

Section

General Articles