Electrodialytic Removal of Cadmium from Brackish Water: Effects of Operating Parameters

Authors

  • Mourad Sik Ali Desalination and Water Treatment Research Unit, Chemistry Department, Faculty of Sciences of Tunis, El Manar II 2092, Tunisia
  • Amor Hafiane Water Researches and Technologies Centre of Borj-Cedria, PO Box 273, 8020 Soliman, Tunisia
  • Mahmoud Dhahbi Water Researches and Technologies Centre of Borj-Cedria, PO Box 273, 8020 Soliman, Tunisia
  • Béchir Hamrouni Desalination and Water Treatment Research Unit, Chemistry Department, Faculty of Sciences of Tunis, El Manar II 2092, Tunisia

DOI:

https://doi.org/10.6000/1929-6037.2014.03.02.1

Keywords:

Electrodialysis, Synthetic brackish water, Demineralization rate, Cadmium removal, Process efficiency.

Abstract

The continuous increase of environmental regulations make interesting to find effective and efficient methods for processing effluents containing metal ions. This research focuses on cadmium removal from brackish water by an electro-membrane process: The electrodialysis. Experiments were carried out on synthetic brackish water solutions and using a laboratory scale electrodialysis system. The influence of several parameters on process efficiency was investigated. The efficiency of this process was assessed by the determination of five parameters: The demineralization rate, the removal rate and the transport flux of cadmium, the current efficiency and the specific power consumption. The applied voltage, the feed flow rate, the pH and cadmium initial concentration of the feed solution have a significant effect on the process efficiency and mainly on the cadmium transfer from dilute to concentrate compartment. In contrast, feed ionic strength seems to affect only the SPC and not the R(Cd).

Author Biography

Béchir Hamrouni, Desalination and Water Treatment Research Unit, Chemistry Department, Faculty of Sciences of Tunis, El Manar II 2092, Tunisia

Chemistry Department

References

World Health Organization. Cadmium in Drinking-water; 2011: Available from: http://www.who.int/water_sanitation_ health/dwq/chemicals/cadmium.pdf

World Health Organization. Guidelines for drinking-water quality.4th ed.; 2011: Available from: http://whqlibdoc.who.int/ publications/2011/9789241548151_eng.pdf

Naushad M, Al-Othman ZA, Islam M. Adsorption of cadmium ion using a new composite cation-exchanger polyaniline Sn(IV) silicate: kinetics, thermodynamic and isotherm studies. Int J Environ Sci Technol 2013; 10: 567-78. http://dx.doi.org/10.1007/s13762-013-0189-0

Abdel Salam M. Removal of heavy metal ions from aqueous solutions with multi-walled carbon nanotubes: Kinetic and thermodynamic studies. Int J Environ Sci Technol 2012: 1-12.

Kumar R, Jain SK, Misra RK, Kachchwaha M, Khatri PK. Aqueous heavy metals removal by adsorption on β-diketone-functionalized styrene–divinylbenzene copolymeric resin. Int J Environ Sci Technol 2012; 9: 79-84. http://dx.doi.org/10.1007/s13762-011-0019-1

Zamani AA, Shokri R, Yaftian MR, Parizanganeh AH. Adsorption of lead, zinc and cadmium ions from contaminated water onto Peganum harmala seeds as biosorbent. Int J Environ Sci Technol 2013; 10: 93-102. http://dx.doi.org/10.1007/s13762-012-0107-x

Ballet GT, Gzara L, Hafiane A, Dhahbi M. Transport coefficients and cadmium salt rejection in nanofiltration membrane. Desalination 2004; 167: 369-76. http://dx.doi.org/10.1016/j.desal.2004.06.148

Jellouli Ennigrou D, Gzara L, Ramzi Ben Romdhane M, Dhahbi M. Cadmium removal from aqueous solutions by polyelectrolyte enhanced ultrafiltration. Desalination 2009; 246: 363-9. http://dx.doi.org/10.1016/j.desal.2008.04.053

Lee G. Effects of operating parameters on the removal performance of electrodialysis for treating wastewater containing cadmium. Desalin Water Treat 2011; 35: 150-7. http://dx.doi.org/10.5004/dwt.2011.2850

Ghyselbrecht K, Huygebaert M, Van der Bruggen B, Ballet R, Meesschaert B, Pinoy L. Desalination of an industrial saline water with conventional and bipolar membrane electrodialysis. Desalination 2013; 318: 9-18. http://dx.doi.org/10.1016/j.desal.2013.03.020

Banasiak LJ, Schäfer AI. Removal of boron, fluoride and nitrate by electrodialysis in the presence of organic matter. J Memb Sci 2009; 334: 101-9. http://dx.doi.org/10.1016/j.memsci.2009.02.020

Moon SH, Yun SH. Process integration of electrodialysis for a cleaner environment. Curr Opin Chem Eng 2014; 4: 25-31. http://dx.doi.org/10.1016/j.coche.2014.01.001

Ben Sik Ali M, Mnif A, Hamrouni B, Dhahbi M. Electrodialytic desalination of brackish water: Effect of process parameters and water characteristics. Ionics 2010; 16: 621-9. http://dx.doi.org/10.1007/s11581-010-0441-2

Baker RW. Membrane technology and applications. 2nd ed. John Wiley & Sons: England 2004. http://dx.doi.org/10.1002/0470020393

Noble RD, Stern SA. Membrane separations technologies Principles and Applications.Elsevier Science: Amsterdam 1995.

Strathmann H. Electrodialysis, a mature technology with a multitude of new applications. Desalination 2010; 264: 268-88. http://dx.doi.org/10.1016/j.desal.2010.04.069

Casademont C, Farias MA, Pourcelly G, Bazinet L. Impact of electrodialytic parameters on cation migration kinetics and fouling nature of ion-exchange membranes during treatment of solutions with different magnesium/calcium ratios. J Memb Sci 2008; 325: 570-9. http://dx.doi.org/10.1016/j.memsci.2008.08.023

Wang Q, Ying T, Jiang T, Yang D, Jahangir MM. Demineralization of soybean oligosaccharides extract from sweet slurry by conventional electrodialysis. J Food Eng 2009; 95: 410-5. http://dx.doi.org/10.1016/j.jfoodeng.2009.05.024

Ergun E, Tor A, Cengeloglu Y, Kocak I. Electrodialytic removal of fluoride from water: Effects of process parameters and accompanying anions. Sep Purif Technol 2008; 64: 147-53. http://dx.doi.org/10.1016/j.seppur.2008.09.009

Lambert J, Avila-Rodriguez M, Durand G, Rakib M. Separation of sodium ions from trivalent chromium by electrodialysis using monovalent cation selective membranes. J Memb Sci 2006; 280: 219-25. http://dx.doi.org/10.1016/j.memsci.2006.01.021

Sadrzadeh M, Razmi A, Mohammadi T. Separation of different ions from wastewater at various operating conditions using electrodialysis. Sep Purif Technol 2007; 54: 147-56. http://dx.doi.org/10.1016/j.seppur.2006.08.023

Ben Sik Ali M, Jellouli Ennigrou D, Hamrouni B. Iron removal from brackish water by electrodialysis. Environ Technol 2013: 1-28.

Ben Sik Ali M, Hamrouni B, Dhahbi M. Electrodialytic defluoridation of brackish water: effect of process parameters and water characteristics. CLEAN – Soil, Air, Water 2010; 38: 623-9.

Puigdomenech I. Medusa Software. KTH Royal Institute of Technology, Department of Chemistry. Sweden; 2010 [cited 2010Dec06]: Available from: http://www.kth.se/en/che/ medusa/chemeq-1.369367

Downloads

Published

2014-06-02

How to Cite

Ali, M. S., Hafiane, A., Dhahbi, M., & Hamrouni, B. (2014). Electrodialytic Removal of Cadmium from Brackish Water: Effects of Operating Parameters. Journal of Membrane and Separation Technology, 3(2), 67–77. https://doi.org/10.6000/1929-6037.2014.03.02.1

Issue

Section

Articles