A Simple Solution of Dissolved Ammonia Recovery Process in a Hollow-Fiber Membrane Contactor: Comparison with Experimental and Numerical Results
DOI:
https://doi.org/10.6000/1929-6037.2019.08.01Keywords:
Ammonia removal, analytical solution, wastewater, hollow-fiber contactor.Abstract
Ammonia in gaseous form is one of the major pollutants in waters and wastewaters. Of all the processes studied so far for the removal of dissolved ammonia from aqueous solution, hollow fiber membrane contactor-based processes have shown great potential. This method has shown to be effective to substantially reducing ammonia concentration to an acceptable value economically and efficiently. Mathematical analysis is presented in this report for the removal of ammonia dissolved in an aqueous phase to a recovery/stripping solution in a hollow fiber membrane contactor (HFMC). The membrane contactor is considered to consist of the lumen side (allowing aqueous flow) and shell side (allowing the flow of the stripping/recovery solution). An approximate analytical solution is derived for the simplified model that does not include radial diffusion of solutes (only axial mass flux is included). The predicted results of this solution are compared with the experimental data and with the numerical results in the literature over a range of operating conditions. The flow rates of the feed solution covered: 2.01 x 10 -9 to 4.7 x 10 -6 m3/s, initial concentration: 50 – 800 ppm and pH values of the solution containing ammonia: 8 - 11. The agreement is very good between the profiles of the simplified analytical solution and the earlier published experimental data. In addition, the results obtained by the analytical solution are close to the numerical solution of the complete model over a good range of operating conditions.
References
Rezakazemi M, Shirazian S, Ashrafizadeh S. Simulation of ammonia removal from industrial wastewater streams by means of hollow –fiber membrane contactor. Desalination 2012; 285: 383-392. https://doi.org/10.1016/j.desal.2011.10.030
Mandowara A, Bhattacharya P. Simulation studies of ammonia removal from water in a membrane contactor under liquid-liquid extraction mode. J Environ Manage 2011; 92: 121-130. https://doi.org/10.1016/j.jenvman.2010.08.015
Mandowara A, Bhattacharya P. Membrane contactor as degasser operated under vacuum for ammonia removal from water: A numerical simulation of mass transfer under laminar flow conditions. Comp Chem Eng 2009; 33: 1123-1131. https://doi.org/10.1016/j.compchemeng.2008.12.005
Tan X, Tan SP, Teo WK, Li K. Polyvinylidene fluoride (PVDF) hollow fiber membranes for ammonia removal from water. J Membr Sci 2006; 271: 59-68. https://doi.org/10.1016/j.memsci.2005.06.057
Kunz A, Mukhtar S. Hydrophobic membrane technology for ammonia extraction from wastewaters. Eng Agric 2016; 36: 1-11. https://doi.org/10.1590/1809-4430-Eng.Agric.v36n2p377-386/2016
Ashrafizadeh SN, Khorasani Z. Ammonia removal from aqueous solutions using hollow-fiber membrane contactors. Chem Eng J 2010; 162: 242-249. https://doi.org/10.1016/j.cej.2010.05.036
Hasanoglu A, Romero J, Perez B, Plaza A. Ammonia removal from wastewater streams through membrane contactors: Experimental and theoretical analysis of operation parameters and configuration. Chem Eng J 2010; 160: 530-537. https://doi.org/10.1016/j.cej.2010.03.064
Licon E, Reig M, Villanova P, Valderrama C. Ammonia removal by liquid-liquid membrane contactor under closed loop regime, Excerpt from the Proceedings of the 2012 COMSOL Conference, Milan, Italy.
Rawat A, Agrahari GK, Pandey N, Bhattacharya PK, Mathematical analysis of removal of dissolved acidic gases from aqueous stream using membrane contactor. Intl J Chem Eng Appl 2013; 4: 290-294. https://doi.org/10.7763/IJCEA.2013.V4.312
Kartohardjono S, Damaiati GM, Rama CT. Effects of absorbents on ammonia removal from wastewater through hollow fiber membrane contactor. J Environ Sci Technol 2015; 8: 225-231. https://doi.org/10.3923/jest.2015.225.231
Kartohardjono S, Fermi MI, Yuliausman, Elkardiana K, Sangaji AP, Ramadhan AM. The removal of dissolved ammonia from wastewater through a polypropylene hollow fiber membrane contactor. Intl J Technol 2015; 7: 1146-1152. https://doi.org/10.14716/ijtech.v6i7.1845
Lai C-L, Chen S-H, Liou R-M. Removing aqueous ammonia by membrane contactor process. Desalination and Water Treatment 2013; 51: 5307-5310. https://doi.org/10.1080/19443994.2013.768788
Norddahl B, Horn VG, Larsson M, du Preez JH, Christensen K. Desalination 2006; 199: 172-174. https://doi.org/10.1016/j.desal.2006.03.037
Kartohardjono S, Herdiana M, Bismo S. Combination of ozonation and absorption through membrane contactor to remove ammonia from wastewater. Jurnal Teknik Indonesia 2012; 81-86.
Amaral MCS, Magalhaes NC, Moravia WG, Ferreira CD. Ammonia recovery from landfill leachate using hydrophobic membrane. Water Sci Technol 2016; 74: 2177-2184. https://doi.org/10.2166/wst.2016.375
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