The Influence of Density on the Mechanical Response of Reinforced High-Density Polyurethane Foams: A Statistical Approach

Authors

  • Eduardo Fischer Kerche Ford Motor Company/Instituto Euvaldo Lodi, Camaçari, Bahia, 42810-225, Brazil and Postgraduate Program in Mining, Metallurgical and Materials Engineering, (PPGE3M) Federal University of Rio Grande do Sul (UFRGS), Porto Alegre, Brazil https://orcid.org/0000-0003-1361-0708
  • Joziel Aparecido da Cruz Postgraduate Program in Mining, Metallurgical and Materials Engineering, (PPGE3M) Federal University of Rio Grande do Sul (UFRGS), Porto Alegre, Brazil
  • Sandro Campos Amico Postgraduate Program in Mining, Metallurgical and Materials Engineering, (PPGE3M) Federal University of Rio Grande do Sul (UFRGS), Porto Alegre, Brazil

DOI:

https://doi.org/10.6000/1929-5995.2022.11.05

Keywords:

Rigid polyurethane foams, high-density foams, micro fibrillated cellulose, cellular composites

Abstract

In this work, rigid polyurethane foams (RPUF) reinforced by micro fibrillated cellulose (MFC) were manufactured using the free rising method and also under confinement inside a closed mould, aiming to increase apparent density and improve mechanical response. Neat RPUF were also manufactured for comparison. The mechanical response, evaluated by compression (following ASTM D1621 standard) tests were correlated with the final composite apparent density (evaluated following ASTM D1622 standard). Simple linear regression statistical models, based on F-test, were developed using stat graphics software, aiming to understand and correlate the increment in density and its influence on the improvement in mechanical response. Different models were developed to describe the foam behavior. The main results show a more significant influence of the density on strength than stiffness for the neat RPUF, unlike the MFC-reinforced RPUF, which presented an opposite response. These effects could be caused by the lower content of voids when the foams were produced under confinement, and by the greater crosslink density, when MFC was added.

References

de A Delucis R, Magalhães, WLE, Petzhold CL, Amico SC. Thermal and combustion features of rigid polyurethane biofoams filled with four forest-based wastes. Pol Comp 2018; 39. https://doi.org/10.1002/pc.24784 DOI: https://doi.org/10.1002/pc.24784

de Avila Delucis R, Kerche EF, Gatto DA, Esteves WLM, Petzhold CL, Amico SC. Surface response and photodegradation performance of bio-based polyurethane-forest derivatives foam composites. Pol Test 2019; 80. https://doi.org/10.1016/j.polymertesting.2019.106102 DOI: https://doi.org/10.1016/j.polymertesting.2019.106102

Kerche EF, Bock DN, Delucis R de A, Magalhães WLE, Amico SC. Micro fibrillated cellulose reinforced bio-based rigid high-density polyurethane foams. Cellulose 2021; 28. https://doi.org/10.1007/s10570-021-03801-1 DOI: https://doi.org/10.1007/s10570-021-03801-1

Nar M, Webber III C, D’Souza NA. Rigid polyurethane and kenaf core composite foams. Pol Eng & Sci 2015; 55. https://doi.org/10.1002/pen.23868 DOI: https://doi.org/10.1002/pen.23868

Kerche EF, Silva VD, Jankee GS, Schrekker HS, Delucis R de A, Irulappasamy S, Amico SC. Aramid pulp treated with imidazolium ionic liquids as a filler in rigid polyurethane bio-foams. J Appl Pol Sci 2021; 138. https://doi.org/10.1002/app.50492 DOI: https://doi.org/10.1002/app.50492

Kerche EF, Delucis RA, Petzhold CL, Amico SC. Rigid bio-based wood/polyurethane foam composites expanded under confinement. J Cell Plas 2021; 57. https://doi.org/10.1177/0021955X20964018 DOI: https://doi.org/10.1177/0021955X20964018

Hamilton AR, Thomsen OT, Madaleno LAO, Jensen LR, Rauhe JCM, Pyrz R. Evaluation of the anisotropic mechanical properties of reinforced polyurethane foams. Comp Sci Tech 2013; 87. https://doi.org/10.1016/j.compscitech.2013.08.013 DOI: https://doi.org/10.1016/j.compscitech.2013.08.013

Członka S, Kerche EF, Neves RM, Strąkowska A, Strzelec K. Bio-Based Rigid Polyurethane Foam Composites Reinforced with Bleached Curauá Fiber. I J Molec Sci 2021; 22. https://doi.org/10.3390/ijms222011203 DOI: https://doi.org/10.3390/ijms222011203

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Published

2022-10-14

How to Cite

Kerche, E. F. ., da Cruz, J. A. ., & Amico, S. C. . (2022). The Influence of Density on the Mechanical Response of Reinforced High-Density Polyurethane Foams: A Statistical Approach. Journal of Research Updates in Polymer Science, 11, 31–35. https://doi.org/10.6000/1929-5995.2022.11.05

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