Volumetric Study of the Binary Mixtures Containing a Branched Hexane and an Isomeric Chlorobutane
Pages 178-184
Hernando Guerrero, Félix M. Royo and Carlos Lafuente

DOI: http://dx.doi.org/10.6000/1929-5030.2015.04.04.3

Published: 17 December 2015

Abstract: This paper reports densities at atmospheric pressure and at three temperatures T = (283.15, 298.15, and 313.15) K of eight binary mixtures involving a branched hexane (3-methylpentane or 2,2-dimethylbutane) and each one of the isomeric chlorobutanes (1-chlorobutane, 2-chlorobutane, 1-chloro-2-methylpropane or 2-chloro-2-methylpropane). Excess volumes were calculated from experimental densities and correlated with the Redlich-Kister equation. Moreover, the excess volumes were analysed using the Prigogine-Flory-Patterson theory.