Journal of Research Updates in Polymer Science

Synthesis by ATRP of Polystyrene-b-Poly(4-vinylpyridine) and Characterization by Inverse Gas Chromatography
Pages 76-89
Mohammad Rajab, Tayssir Hamieh, Aissam Airoudj, Karine Mougin, Kamal Hariri, Wassim Rammal, Houssein Mortada, Mariam Akil, Ahmad Kassas and Joumana Toufaily

DOI: http://dx.doi.org/10.6000/1929-5995.2017.06.03.2

Published: 04 October 2017


Abstract: In this work we propose the use of a hydro-dispersible polymer such as the poly vinyl acetate as a binder for the production of electrodes for lithium-ion batteries. To increase the film forming properties of the polymer the poly vinyl was added with triacetin that acts as a plasticizer. The electrochemical stability of the polymer was tested by a polarizing electrode, formed by mixing the polymer with carbon. Subsequently, an electrode tape was prepared by using LiNi0.5Mn1.5O4 as the active material and characterized by SEM, EDS and TGA. Lithium metal cells were assembled and tested to evaluate specific capacity, power and energy density at various discharge rates. The cycle life of the cell was evaluated by galvanostatic charge/discharge cycles. The tests showed that the electrodes prepared with PVA plasticized with triacetin have very good electrochemical performance in terms of capacity retention as a function of the discharge rate and the cycle number. Our work demonstrates that the use of triacetin to plasticize the PVA allows to increase the electrochemical stability of the electrode likely due to an improvement of the slurry filmability. The proposed method could represent a promising technology for the production of long-term performance lithium batteries..

Keywords: Radical polymerization, Polystyrene-b-Poly(4-vinylpyridine), Inverse Gas Chromatography, Specific interactions, Acid and Base Constants.

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